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Aluminium monofluoride

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Aluminium monofluoride
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IUPAC name
Aluminium monofluoride
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13595-82-9 7pxY
ChEBI CHEBI:49464 7pxY
ChemSpider 4576555 7pxN
Jmol-3D images Image
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PubChem Template:Chembox PubChem/format
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AlF
Molar mass 45.98 g/mol
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Other anions
aluminium monochloride
Other cations
lithium fluoride, sodium fluoride, potassium fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Aluminium monofluoride is the chemical substance with the formula AlF. This elusive species is formed by the reaction between aluminium trifluoride and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled.[1] Clusters derived from related aluminium(I) halides can be stabilized using specialized ligands.[2]

This molecule has been detected in the interstellar medium, where molecules are so dilute that intermolecular collisions are unimportant.[3]

References

  1. Dyke, C.Kirby; Morris, B.W.J.Gravenor (1984). "A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy". Chemical Physics 88 (2): 289. Bibcode:1984CP.....88..289D. doi:10.1016/0301-0104(84)85286-6. 
  2. Dohmeier, C.; Loos, D.; Schnöckel, H. (1996). "Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions". Angewandte Chemie International Edition in English 35 (2): 129–149. doi:10.1002/anie.199601291. 
  3. L. M. Ziurys, A. J. Apponi, T. G. Phillips (1994). "Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF". Astrophysical Journal 433 (2): 729–732. Bibcode:1994ApJ...433..729Z. doi:10.1086/174682. 

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