Open Access Articles- Top Results for Anthocyanidin


Not to be confused with anthocyanins, the sugar-containing counterparts of anthocyanidins.
Molecule in 3D of the anthocyanidin cyanidin

Anthocyanidins are common plant pigments. They are the sugar-free counterparts of anthocyanins based on the flavylium ion or 2-phenylchromenylium, which is a type of oxonium ion (chromenylium is referred also to as benzopyrylium).[1] They form a large group of polymethine dye. In particular anthocyanidins are salt derivatives of the 2-phenylchromenylium cation, also known as flavylium cation. As shown in the figure below, the phenyl group at the 2-position can carry different substituents. The counterion of the flavylium cation is mostly chloride. With this positive charge, the anthocyanidins differ from other flavonoids.


The stability of anthocyanidins is dependent on pH. At a low pH (acidic conditions), colored anthocyanidins are present, whereas at a higher pH (basic conditions) the colorless chalcones forms are present.


3-Deoxyanthocyanidins such as luteolinidin are a class of anthocyanidins lacking an hydroxyl group on carbon 3.

Selected anthocyanidins and their substitutions
Anthocyanidin Basic structure (R4' = −OH) R3' R5' R3 R5 R6 R7
Aurantinidin Basic structure of Anthocyans: The flavio-cation −H −H −OH −OH −OH −OH
Capensinidin −OCH3 −OCH3 −OH −OCH3 −H −OH
Cyanidin −OH −H −OH −OH −H −OH
Delphinidin −OH −OH −OH −OH −H −OH
Europinidin −OCH3 −OH −OH −OCH3 −H −OH
Hirsutidin −OCH3 −OCH3 −OH −OH −H −OCH3
Malvidin −OCH3 −OCH3 −OH −OH −H −OH
Pelargonidin −H −H −OH −OH −H −OH
Peonidin −OCH3 −H −OH −OH −H −OH
Petunidin −OH −OCH3 −OH −OH −H −OH
Pulchellidin −OH −OH −OH −OCH3 −H −OH
Rosinidin −OCH3 −H −OH −OH −H −OCH3


External links

16x16px Media related to Anthocyanidins at Wikimedia Commons