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Atmospheric dispersion modeling
Atmospheric dispersion modeling is the mathematical simulation of how air pollutants disperse in the ambient atmosphere. It is performed with computer programs that solve the mathematical equations and algorithms which simulate the pollutant dispersion. The dispersion models are used to estimate or to predict the downwind concentration of air pollutants or toxins emitted from sources such as industrial plants, vehicular traffic or accidental chemical releases.
Such models are important to governmental agencies tasked with protecting and managing the ambient air quality. The models are typically employed to determine whether existing or proposed new industrial facilities are or will be in compliance with the National Ambient Air Quality Standards (NAAQS) in the United States and other nations. The models also serve to assist in the design of effective control strategies to reduce emissions of harmful air pollutants. During the late 1960s, the Air Pollution Control Office of the U.S. EPA initiated research projects that would lead to the development of models for the use by urban and transportation planners.^{[1]} A major and significant application of a roadway dispersion model that resulted from such research was applied to the Spadina Expressway of Canada in 1971.
Air dispersion models are also used by public safety responders and emergency management personnel for emergency planning of accidental chemical releases. Models are used to determine the consequences of accidental releases of hazardous or toxic materials, Accidental releases may result fires, spills or explosions that involve hazardous materials, such as chemicals or radionuclides. The results of dispersion modeling, using worst case accidental release source terms and meteorological conditions, can provide an estimate of location impacted areas, ambient concentrations, and be used to determine protective actions appropriate in the event a release occurs. Appropriate protective actions may include evacuation or shelter in place for persons in the downwind direction. At industrial facilities, this type of consequence assessment or emergency planning is required under the Clean Air Act (United States) (CAA) codified in Part 68 of Title 40 of the Code of Federal Regulations.
The dispersion models vary depending on the mathematics used to develop the model, but all require the input of data that may include:
 Meteorological conditions such as wind speed and direction, the amount of atmospheric turbulence (as characterized by what is called the "stability class"), the ambient air temperature, the height to the bottom of any inversion aloft that may be present, cloud cover and solar radiation.
 Source term (the concentration or quantity of toxins in emission or accidental release source terms) and temperature of the material
 Emissions or release parameters such as source location and height, type of source (i.e., fire, pool or vent stack)and exit velocity, exit temperature and mass flow rate or release rate.
 Terrain elevations at the source location and at the receptor location(s), such as nearby homes, schools, businesses and hospitals.
 The location, height and width of any obstructions (such as buildings or other structures) in the path of the emitted gaseous plume, surface roughness or the use of a more generic parameter "rural" or "city" terrain.
Many of the modern, advanced dispersion modeling programs include a preprocessor module for the input of meteorological and other data, and many also include a postprocessor module for graphing the output data and/or plotting the area impacted by the air pollutants on maps. The plots of areas impacted may also include isopleths showing areas of minimal to high concentrations that define areas of the highest health risk. The isopleths plots are useful in determining protective actions for the public and responders.
The atmospheric dispersion models are also known as atmospheric diffusion models, air dispersion models, air quality models, and air pollution dispersion models.
Contents
Atmospheric layers
Discussion of the layers in the Earth's atmosphere is needed to understand where airborne pollutants disperse in the atmosphere. The layer closest to the Earth's surface is known as the troposphere. It extends from sealevel to a height of about 18 km and contains about 80 percent of the mass of the overall atmosphere. The stratosphere is the next layer and extends from 18 km to about 50 km. The third layer is the mesosphere which extends from 50 km to about 80 km. There are other layers above 80 km, but they are insignificant with respect to atmospheric dispersion modeling.
The lowest part of the troposphere is called the atmospheric boundary layer (ABL) or the planetary boundary layer (PBL) and extends from the Earth's surface to about 1.5 to 2.0 km in height. The air temperature of the atmospheric boundary layer decreases with increasing altitude until it reaches what is called the inversion layer (where the temperature increases with increasing altitude) that caps the atmospheric boundary layer. The upper part of the troposphere (i.e., above the inversion layer) is called the free troposphere and it extends up to the 18 km height of the troposphere.
The ABL is of the most important with respect to the emission, transport and dispersion of airborne pollutants. The part of the ABL between the Earth's surface and the bottom of the inversion layer is known as the mixing layer. Almost all of the airborne pollutants emitted into the ambient atmosphere are transported and dispersed within the mixing layer. Some of the emissions penetrate the inversion layer and enter the free troposphere above the ABL.
In summary, the layers of the Earth's atmosphere from the surface of the ground upwards are: the ABL made up of the mixing layer capped by the inversion layer; the free troposphere; the stratosphere; the mesosphere and others. Many atmospheric dispersion models are referred to as boundary layer models because they mainly model air pollutant dispersion within the ABL. To avoid confusion, models referred to as mesoscale models have dispersion modeling capabilities that extend horizontally up to a few hundred kilometres. It does not mean that they model dispersion in the mesosphere.
Gaussian air pollutant dispersion equation
The technical literature on air pollution dispersion is quite extensive and dates back to the 1930s and earlier. One of the early air pollutant plume dispersion equations was derived by Bosanquet and Pearson.^{[2]} Their equation did not assume Gaussian distribution nor did it include the effect of ground reflection of the pollutant plume.
Sir Graham Sutton derived an air pollutant plume dispersion equation in 1947^{[3]} which did include the assumption of Gaussian distribution for the vertical and crosswind dispersion of the plume and also included the effect of ground reflection of the plume.
Under the stimulus provided by the advent of stringent environmental control regulations, there was an immense growth in the use of air pollutant plume dispersion calculations between the late 1960s and today. A great many computer programs for calculating the dispersion of air pollutant emissions were developed during that period of time and they were called "air dispersion models". The basis for most of those models was the Complete Equation For Gaussian Dispersion Modeling Of Continuous, Buoyant Air Pollution Plumes shown below:^{[4]}^{[5]}
<math>C = \frac{\;Q}{u}\cdot\frac{\;f}{\sigma_y\sqrt{2\pi}}\;\cdot\frac{\;g_1 + g_2 + g_3}{\sigma_z\sqrt{2\pi}}</math>
where:  
<math>f</math>  = crosswind dispersion parameter 

= <math>\exp\;[\,y^2/\,(2\;\sigma_y^2\;)\;]</math>  
<math>g</math>  = vertical dispersion parameter = <math>\,g_1 + g_2 + g_3</math> 
<math>g_1</math>  = vertical dispersion with no reflections 
= <math>\; \exp\;[\,(z  H)^2/\,(2\;\sigma_z^2\;)\;]</math>  
<math>g_2</math>  = vertical dispersion for reflection from the ground 
= <math>\;\exp\;[\,(z + H)^2/\,(2\;\sigma_z^2\;)\;]</math>  
<math>g_3</math>  = vertical dispersion for reflection from an inversion aloft 
= <math>\sum_{m=1}^\infty\;\big\{\exp\;[\,(z  H  2mL)^2/\,(2\;\sigma_z^2\;)\;]</math>  
<math>+\, \exp\;[\,(z + H + 2mL)^2/\,(2\;\sigma_z^2\;)\;]</math>  
<math>+\, \exp\;[\,(z + H  2mL)^2/\,(2\;\sigma_z^2\;)\;]</math>  
<math>+\, \exp\;[\,(z  H + 2mL)^2/\,(2\;\sigma_z^2\;)\;]\big\}</math>  
<math>C</math>  = concentration of emissions, in g/m³, at any receptor located: 
x meters downwind from the emission source point  
y meters crosswind from the emission plume centerline  
z meters above ground level  
<math>Q_{}</math>  = source pollutant emission rate, in g/s 
<math>u</math>  = horizontal wind velocity along the plume centerline, m/s 
<math>H</math>  = height of emission plume centerline above ground level, in m 
<math>\sigma_z</math>  = vertical standard deviation of the emission distribution, in m 
<math>\sigma_y</math>  = horizontal standard deviation of the emission distribution, in m 
<math>L_{}</math>  = height from ground level to bottom of the inversion aloft, in m 
<math>\exp</math>  = the exponential function 
The above equation not only includes upward reflection from the ground, it also includes downward reflection from the bottom of any inversion lid present in the atmosphere.
The sum of the four exponential terms in <math>g_3</math> converges to a final value quite rapidly. For most cases, the summation of the series with m = 1, m = 2 and m = 3 will provide an adequate solution.
<math>\sigma_z</math> and <math>\sigma_y</math> are functions of the atmospheric stability class (i.e., a measure of the turbulence in the ambient atmosphere) and of the downwind distance to the receptor. The two most important variables affecting the degree of pollutant emission dispersion obtained are the height of the emission source point and the degree of atmospheric turbulence. The more turbulence, the better the degree of dispersion.
The resulting calculations for air pollutant concentrations are often expressed as an air pollutant concentration contour map in order to show the spatial variation in contaminant levels over a wide area under study. In this way the contour lines can overlay sensitive receptor locations and reveal the spatial relationship of air pollutants to areas of interest.
Whereas older models rely on stability classes (see air pollution dispersion terminology) for the determination of <math>\sigma_y</math> and <math>\sigma_z</math>, more recent models increasingly rely on the MoninObukhov similarity theory to derive these parameters.
Briggs plume rise equations
The Gaussian air pollutant dispersion equation (discussed above) requires the input of H which is the pollutant plume's centerline height above ground level—and H is the sum of H_{s} (the actual physical height of the pollutant plume's emission source point) plus ΔH (the plume rise due the plume's buoyancy).
To determine ΔH, many if not most of the air dispersion models developed between the late 1960s and the early 2000s used what are known as "the Briggs equations." G.A. Briggs first published his plume rise observations and comparisons in 1965.^{[6]} In 1968, at a symposium sponsored by CONCAWE (a Dutch organization), he compared many of the plume rise models then available in the literature.^{[7]} In that same year, Briggs also wrote the section of the publication edited by Slade^{[8]} dealing with the comparative analyses of plume rise models. That was followed in 1969 by his classical critical review of the entire plume rise literature,^{[9]} in which he proposed a set of plume rise equations which have become widely known as "the Briggs equations". Subsequently, Briggs modified his 1969 plume rise equations in 1971 and in 1972.^{[10]}^{[11]}
Briggs divided air pollution plumes into these four general categories:
 Cold jet plumes in calm ambient air conditions
 Cold jet plumes in windy ambient air conditions
 Hot, buoyant plumes in calm ambient air conditions
 Hot, buoyant plumes in windy ambient air conditions
Briggs considered the trajectory of cold jet plumes to be dominated by their initial velocity momentum, and the trajectory of hot, buoyant plumes to be dominated by their buoyant momentum to the extent that their initial velocity momentum was relatively unimportant. Although Briggs proposed plume rise equations for each of the above plume categories, it is important to emphasize that "the Briggs equations" which become widely used are those that he proposed for bentover, hot buoyant plumes.
In general, Briggs's equations for bentover, hot buoyant plumes are based on observations and data involving plumes from typical combustion sources such as the flue gas stacks from steamgenerating boilers burning fossil fuels in large power plants. Therefore the stack exit velocities were probably in the range of 20 to 100 ft/s (6 to 30 m/s) with exit temperatures ranging from 250 to 500 °F (120 to 260 °C).
A logic diagram for using the Briggs equations^{[4]} to obtain the plume rise trajectory of bentover buoyant plumes is presented below:
where: Δh = plume rise, in m F^{ } = buoyancy factor, in m^{4}s^{−3} x = downwind distance from plume source, in m x_{f} = downwind distance from plume source to point of maximum plume rise, in m u = windspeed at actual stack height, in m/s s^{ } = stability parameter, in s^{−2}
The above parameters used in the Briggs' equations are discussed in Beychok's book.^{[4]}
See also
Atmospheric dispersion models
 List of atmospheric dispersion models provides a more comprehensive list of models than listed below. It includes a very brief description of each model.
 ADMS
 AERMOD
 ATSTEP
 CALPUFF
 CMAQ
 DISPERSION21
 FLACS
 FLEXPART
 HYSPLIT
 HYPACT
 ISC3
 NAME
 MERCURE
 OSPM
 RIMPUFF
 SAFE AIR
 PUFFPLUME
Organizations
 Air Quality Modeling Group
 Air Resources Laboratory
 Finnish Meteorological Institute
 KNMI, Royal Dutch Meteorological Institute
 National Environmental Research Institute of Denmark
 Swedish Meteorological and Hydrological Institute
 TA Luft
 UK Atmospheric Dispersion Modelling Liaison Committee
 UK Dispersion Modelling Bureau
 Desert Research Institute
Others
 Air pollution dispersion terminology
 List of atmospheric dispersion models
 Portable Emissions Measurement System (PEMS)
 Roadway air dispersion modeling
 Useful conversions and formulas for air dispersion modeling
References
 ^ Fensterstock, J.C. et al., "Reduction of air pollution potential through environmental planning", JAPCA, Vol.21,No.7, 1971.
 ^ Bosanquet, C.H. and Pearson, J.L., "The spread of smoke and gases from chimneys", Trans. Faraday Soc., 32:1249, 1936
 ^ Sutton, O.G., "The problem of diffusion in the lower atmosphere", QJRMS, 73:257, 1947 and "The theoretical distribution of airborne pollution from factory chimneys", QJRMS, 73:426, 1947
 ^ ^{a} ^{b} ^{c} Beychok, Milton R. (2005). Fundamentals Of Stack Gas Dispersion (4th Edition ed.). authorpublished. ISBN 0964458802.
 ^ Turner, D.B. (1994). Workbook of atmospheric dispersion estimates: an introduction to dispersion modeling (2nd Edition ed.). CRC Press. ISBN 156670023X.
 ^ Briggs, G.A., "A plume rise model compared with observations", JAPCA, 15:433–438, 1965
 ^ Briggs, G.A., "CONCAWE meeting: discussion of the comparative consequences of different plume rise formulas", Atmos. Envir., 2:228–232, 1968
 ^ Slade, D.H. (editor), "Meteorology and atomic energy 1968", Air Resources Laboratory, U.S. Dept. of Commerce, 1968
 ^ Briggs, G.A., "Plume Rise", USAEC Critical Review Series, 1969
 ^ Briggs, G.A., "Some recent analyses of plume rise observation", Proc. Second Internat'l. Clean Air Congress, Academic Press, New York, 1971
 ^ Briggs, G.A., "Discussion: chimney plumes in neutral and stable surroundings", Atmos. Envir., 6:507–510, 1972
Further reading
Books
 Introductory
 Beychok, Milton R. (2005). Fundamentals Of Stack Gas Dispersion (4th Edition ed.). authorpublished. ISBN 0964458802.
 Center for Chemical Process Safety (1999). Guidelines for Chemical Process Quantitative Risk Analysis (2nd Edition ed.). American Institute of Chemical Engineers, New York, NY. ISBN 9780816907205.
 Center for Chemical Process Safety (1996). Guidelines for Use of Vapor Cloud and Source Dispersion Models, with Worked Examples (2nd Edition ed.). American Institute of Chemical Engineers, New York, NY. ISBN 9780816907021.
 Schnelle, Karl B. and Dey, Partha R. (1999). Atmospheric Dispersion Modeling Compliance Guide (1st Edition ed.). McGrawHill Professional. ISBN 0070580596.
 Turner, D.B. (1994). Workbook of Atmospheric Dispersion Estimates: An Introduction to Dispersion Modeling (2nd Edition ed.). CRC Press. ISBN 156670023X.
 Advanced
 Arya, S. Pal (1998). Air Pollution Meteorology and Dispersion (1st Edition ed.). Oxford University Press. ISBN 0195073983.
 Barrat, Rod (2001). Atmospheric Dispersion Modelling (1st Edition ed.). Earthscan Publications. ISBN 1853836427.
 Colls, Jeremy (2002). Air Pollution (1st Edition ed.). Spon Press (UK). ISBN 0415255651.
 Cooper, J.R., Randle, K. and Sokh, R.G. (2003). Radioactive Releases in the Environment (1st Edition ed.). John Wiley & Sons. ISBN 0471899240.
 European Process Safety Centre (1999). Atmospheric Dispersion (1st Edition ed.). Rugby: Institution of Chemical Engineers. ISBN 0852954042.
 Godish, Thad (2003). Air Quality (4th Edition ed.). CRC Press. ISBN 156670586X.
 Hanna, S.R. and Drivas, D. G. (1996). Guidelines for Use of Vapor Cloud Dispersion Models (2nd Edition ed.). WileyAmerican Institute of Chemical Engineers. ISBN 0816907021.
 Hanna, S. R. and Strimaitis, D. G. (1989). Workbook of Test Cases for Vapor Cloud Source Dispersion Models (1st Edition ed.). Center for Chemical Process Safety, American Institute of Chemical Engineers. ISBN 0816904553.
 Hanna, S. R. and Britter, R.E. (2002). Wind Flow and Vapor Cloud Dispersion at Industrial and Urban Sites (1st Edition ed.). WileyAmerican Institute of Chemical Engineers. ISBN 081690863X.
 Perianez, Raul (2005). Modelling the dispersion of radionuclides in the marine environment : an introduction (1st Edition ed.). Springer. ISBN 3540248757.
 Pielke, Roger A. (2001). Mesoscale Modeling (2nd Edition ed.). Elsevier. ISBN 0125547668.
 Zannetti, P. (1990). Air pollution modeling : theories, computational methods, and available software. Van Nostrand Reinhold. ISBN 0442308051.
Proceedings
 Editors: Forago, I., Georgiev, K. and Havasi, A. (2004). Advances in Air Pollution Modeling for Environmental Security (NATO Workshop). Springer, 2005. ISSN 09574352.
 Editors: Kretzschmar, J. G. and Cosemans, G. (1996). Harmonization within atmospheric dispersion modelling for regulatory purposes (4th Workshop). International Journal of Environment and Pollution, vol. 8 no. 3–6, Interscience Enterprises, 1997. ISSN 09574352.
 Editor: Bartzis, J G. (1998). Harmonization within atmospheric dispersion modelling for regulatory purposes (5th Workshop). International Journal of Environment and Pollution, vol. 14 no. 1–6, Interscience Enterprises, 2000. ISSN 09574352.
 Editor: Coppalle, A. (1999). Harmonization within atmospheric dispersion modelling for regulatory purposes (6th Workshop). International Journal of Environment and Pollution, vol. 16 no. 1–6, Inderscience Enterprises, 2001. ISSN 09574352.
 Editor: Batchvarova, E. (2002). Harmonization within atmospheric dispersion modelling for regulatory purposes (8th Workshop). International Journal of Environment and Pollution, vol. 20 no. 1–6, Inderscience Enterprises, 2003. ISSN 09574352.
 Editor: Suppan, P. (2004). Harmonization within atmospheric dispersion modelling for regulatory purposes (8th Workshop). International Journal of Environment and Pollution, vol. 24 no. 1–6 and vol.25 no. 1–6, Inderscience Enterprises, 2005. ISSN 09574352.
 Editor: Zannetti, P. et al. (1993). International Conference on Air Pollution (1st, Mexico City). Computational Mechanics, 1993. ISBN 1562521462.
 Editor: De Wispelaere, C. (1980). International Technical Meeting on Air Pollution Modeling and Its Application (11th). Plenum Press, 1981. ISBN 0306408201.
 Editor: De Wispelaere, C. (1982). International Technical Meeting on Air Pollution Modeling and Its Application (13th). NATO Committee on the Challenges of Modern Society [by] Plenum Press, 1984. ISBN 0306414910.
 Editors: Gryning, S. and Schiermeir, F.A. (1995). International Technical Meeting on Air Pollution Modeling and Its Application (21st). NATO Committee on the Challenges of Modern Society [by] Plenum Press, 1996. ISBN 0306453819.
 Editors: Gryning, S. and Chaumerliac, N. (1997). International Technical Meeting on Air Pollution Modeling and Its Application (22nd). NATO Committee on the Challenges of Modern Society [by] Plenum Press, 1998. ISBN 0306458217.
 Editors: Gryning, S. and Batchvarova, E. (1998). International Technical Meeting on Air Pollution Modeling and Its Application (23rd). NATO Committee on the Challenges of Modern Society [by] Kluwer Academic/Plenum Press, 2000. ISBN 0306461889.
 Editors: Gryning, S. and Schiermeir, F.A. (2000). International Technical Meeting on Air Pollution Modeling and Its Application (24th). NATO Committee on the Challenges of Modern Society [by] Kluwer Academic, 2001. ISBN 0306465345.
 Editors:Borrego, C. and Schayes, G. (2000). International Technical Meeting on Air Pollution Modeling and Its Application (25th). NATO Committee on the Challenges of Modern Society [by] Kluwer Academic, 2002. ISBN 0306472945.
 Editors:Borrego, C. and Incecik, S. (2003). International Technical Meeting on Air Pollution Modeling and Its Application (26th). NATO Committee on the Challenges of Modern Society [by] Kluwer Academic/Plenum Press, 2004. ISBN 0306484641.
 Editors:Committee on the Atmospheric Dispersion of Hazardous Material Releases, National Research Council (2002). Tracking and Predicting the Atmospheric Dispersion of Hazardous Material Releases (Workshop). National Academies Press, 2003. ISBN 0309089263.
Guidance
 Hanna, S. R., Briggs, G. A., & Hosker, R. P. (1982). Handbook on Atmopheric Diffusion. U.S. Department of Energy, Technical Information Center. DOE/TIC11223.
 U.S. Environmental Protection Agency (1993). Guidance on the Application of Refined Dispersion Models for Hazardous/Toxic Air Releases. Office of Air Quality Planning and Standards, EPA454/R93002.
 U.S. Environmental Protection Agency (1999). Risk Management Program Guidance for Offsite Consequence Analysis (Appendices) (PDF). Office of Solid Waste and Emergency Response, EPA 550B99009.
 U.S. Environmental Protection Agency (1999). Technical Background Document for Offsite Consequence Analysis for Anhydrous Ammonia, Aqueous Ammonia, Chlorine, and Sulfur Dioxide (PDF). Chemical Emergency Preparedness and Prevention Office.
 U.S. Environmental Protection Agency (2009). Chapter 4: Offsite Consequence Analysis. In General Guidance on Risk Management Programs for Chemical Accident Prevention (40 CFR Part 68) (PDF). Office of Solid Waste and Emergency Response, EPA 555B04001.
External links
 EPA's Support Center for Regulatory Atmospheric Modeling
 EPA's Air Quality Modeling Group (AQMG)
 NOAA's Air Resources Laboratory (ARL)
 The Open Directory Project has a good amount of dispersion modeling information
 UK Atmospheric Dispersion Modelling Liaison Committee web site
 UK Dispersion Modelling Bureau web site
 Atmospheric Chemistry transport model LOTOSEUROS
 The Operational Priority Substances model OPS Invalid language code.
 HAMSGPS Dispersion modelling
 Wiki on Atmospheric Dispersion Modelling. Addresses the international community of atmospheric dispersion modellers  primarily researchers, but also users of models. Its purpose is to pool experiences gained by dispersion modellers during their work.
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