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Brazilin

Brazilin
Skeletal formula of brazilin
Space-filling model of the brazilin molecule
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IUPAC name
(6aS,11bR)-7,11b-Dihydro-6H-indeno[2,1-c]chromene-3,6a,9,10-tetrol
Other names
Brasilin; Natural Red 24
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474-07-7 7pxN
ChEBI CHEBI:3170 7pxY
ChEMBL ChEMBL598951 7pxY
ChemSpider 66104 7pxY
Jmol-3D images Image
Image
PubChem Template:Chembox PubChem/format
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C16H14O5
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Infobox references

Brazilin is a red pigment obtained from the wood of the brazilwood family (Caesalpinia sp), and is also known as Natural Red 24. Brazilin has been used since at least the Middle Ages to dye fabric, and has been used to make paints and inks as well. The specific color produced by the pigment depends on its manner of preparation: in an acidic solution brazilin will appear yellow, but in an alkaline preparation it will appear red. Brazilin is closely related to the blue-black dye hematoxylin, having one fewer hydroxyl group. Brazilein is the name for the oxidized pigment.[1]

Sources of brazilin

Many members of the genus Caesalpinia produce brazilin, including brazilwood (C. echinata) and sappanwood (C. sappan). The sappanwood is found in India, Malaysia, and Sri Lanka, the latter being a major supplier of the wood to Europe during the early Middle Ages. Later, discovery of brazilwood in the new world led to its rise in popularity with the dye industry and eventually its over-exploitation. Brazilwood is now classified as an endangered species.

Extraction and preparation

There are many ways to extract and prepare brazilin. A common recipe, developed in the Middle Ages, is to first powder the brazilwood, turning it into sawdust. Then, the powder can be soaked in lye (which produces a deep, purplish red) or a hot solution of alum (which produces an orange-red color), either of which extracts the color better than plain water alone. To the lye extract, alum is added (or to the alum extract, lye) in order to fix the color, which will precipitate from the solution. The precipitate can be dried and powdered, and is a type of lake pigment.

Like many lake pigments, the exact colors produced depends on the pH of the mixture and the fixative used. Aluminum mordants used with brazilin produce the standard red colors, while the use of a tin mordant, in the form of SnCl2 or SnCl4 added to the extract is capable of yielding a pink color.

An alternative preparation which produces a transparent red color involves soaking the brazilwood powder in glair or a solution of gum arabic. Alum is added to help develop and fix the color, which can then be used as a transparent ink or paint.

As with hematoxylin, brazilin can be used for staining cell nuclei in histological preparations when combined with aluminum. The nuclei are then colored red instead of blue.

Notes

  1. ^ De Oliveira, Luiz F.C.; Edwards, Howell G.M.; Velozo, Eudes S.; Nesbitt, M. (2002). "Vibrational spectroscopic study of brazilin and brazilein, the main constituents of brazilwood from Brazil". Vibrational Spectroscopy 28 (2): 243. doi:10.1016/S0924-2031(01)00138-2. 

References

  • The Merck Index, 12th Edition. 1392
  • Armstrong, Wayne P. (1994). "Natural Dyes". HerbalGram 32: 30. 
  • Thompson, Daniel V. The Materials and Techniques of Medieval Painting, Dover Publications, Inc. New York, NY. 1956.

External links

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