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Quantum field theory 

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In theoretical physics, quantum field theory (QFT) is a theoretical framework for constructing quantum mechanical models of subatomic particles in particle physics and quasiparticles in condensed matter physics. A QFT treats particles as excited states of an underlying physical field, so these are called field quanta.
For example, quantum electrodynamics (QED) has one electron field and one photon field; quantum chromodynamics (QCD) has one field for each type of quark; and, in condensed matter, there is an atomic displacement field that gives rise to phonon particles. Edward Witten describes QFT as "by far" the most difficult theory in modern physics.^{[1]}
In QFT, quantum mechanical interactions between particles are described by interaction terms between the corresponding underlying fields. QFT interaction terms are similar in spirit to those between charges with electric and magnetic fields in Maxwell's equations. However, unlike the classical fields of Maxwell's theory, fields in QFT generally exist in quantum superpositions of states and are subject to the laws of quantum mechanics.
Ordinary quantum mechanical systems have a fixed number of particles, with each particle having a finite number of degrees of freedom. In contrast, the excited states of a QFT can represent any number of particles. This makes quantum field theories especially useful for describing systems where the particle count/number may change over time, a crucial feature of relativistic dynamics.
Because the fields are continuous quantities over space, there exist excited states with arbitrarily large numbers of particles in them, providing QFT systems with an effectively infinite number of degrees of freedom. Infinite degrees of freedom can easily lead to divergences of calculated quantities (i.e., the quantities become infinite). Techniques such as renormalization of QFT parameters or discretization of spacetime, as in lattice QCD, are often used to avoid such infinities so as to yield physically meaningful results.
Most theories in standard particle physics are formulated as relativistic quantum field theories, such as QED, QCD, and the Standard Model. QED, the quantum fieldtheoretic description of the electromagnetic field, approximately reproduces Maxwell's theory of electrodynamics in the lowenergy limit, with small nonlinear corrections to the Maxwell equations required due to virtual electron–positron pairs.
In the perturbative approach to quantum field theory, the full field interaction terms are approximated as a perturbative expansion in the number of particles involved. Each term in the expansion can be thought of as forces between particles being mediated by other particles. In QED, the electromagnetic force between two electrons is caused by an exchange of photons. Similarly, intermediate vector bosons mediate the weak force and gluons mediate the strong force in QCD. The notion of a forcemediating particle comes from perturbation theory, and does not make sense in the context of nonperturbative approaches to QFT, such as with bound states.
The gravitational field and the electromagnetic field are the only two fundamental fields in nature that have infinite range and a corresponding classical lowenergy limit, which greatly diminishes and hides their "particlelike" excitations. Albert Einstein in 1905, attributed "particlelike" and discrete exchanges of momenta and energy, characteristic of "field quanta", to the electromagnetic field. Originally, his principal motivation was to explain the thermodynamics of radiation. Although the photoelectric effect and Compton scattering strongly suggest the existence of the photon, it might alternately be explained by a mere quantization of emission; more definitive evidence of the quantum nature of radiation is now taken up into modern quantum optics as in the antibunching effect.^{[2]}
There is currently no complete quantum theory of the remaining fundamental force, gravity. Many of the proposed theories to describe gravity as a QFT postulate the existence of a graviton particle that mediates the gravitational force. Presumably, the as yet unknown correct quantum fieldtheoretic treatment of the gravitational field will behave like Einstein's general theory of relativity in the lowenergy limit. Quantum field theory of the fundamental forces itself has been postulated to be the lowenergy effective field theory limit of a more fundamental theory such as superstring theory.
Contents
History
Foundations
The early development of the field involved Dirac, Fock, Pauli, Heisenberg and Bogolyubov. This phase of development culminated with the construction of the theory of quantum electrodynamics in the 1950s.
Gauge theory
Gauge theory was formulated and quantized, leading to the unification of forces embodied in the standard model of particle physics. This effort started in the 1950s with the work of Yang and Mills, was carried on by Martinus Veltman and a host of others during the 1960s and completed by the 1970s through the work of Gerard 't Hooft, Frank Wilczek, David Gross and David Politzer.
Grand synthesis
Parallel developments in the understanding of phase transitions in condensed matter physics led to the study of the renormalization group. This in turn led to the grand synthesis of theoretical physics, which unified theories of particle and condensed matter physics through quantum field theory. This involved the work of Michael Fisher and Leo Kadanoff in the 1970s, which led to the seminal reformulation of quantum field theory by Kenneth G. Wilson in 1975.
Principles
Classical and quantum fields
A classical field is a function defined over some region of space and time.^{[3]} Two physical phenomena which are described by classical fields are Newtonian gravitation, described by Newtonian gravitational field g(x, t), and classical electromagnetism, described by the electric and magnetic fields E(x, t) and B(x, t). Because such fields can in principle take on distinct values at each point in space, they are said to have infinite degrees of freedom.^{[3]}
Classical field theory does not, however, account for the quantummechanical aspects of such physical phenomena. For instance, it is known from quantum mechanics that certain aspects of electromagnetism involve discrete particles—photons—rather than continuous fields. The business of quantum field theory is to write down a field that is, like a classical field, a function defined over space and time, but which also accommodates the observations of quantum mechanics. This is a quantum field.
It is not immediately clear how to write down such a quantum field, since quantum mechanics has a structure very unlike a field theory. In its most general formulation, quantum mechanics is a theory of abstract operators (observables) acting on an abstract state space (Hilbert space), where the observables represent physically observable quantities and the state space represents the possible states of the system under study.^{[4]} For instance, the fundamental observables associated with the motion of a single quantum mechanical particle are the position and momentum operators <math>\hat{x}</math> and <math>\hat{p}</math>. Field theory, in contrast, treats x as a way to index the field rather than as an operator.^{[5]}
There are two common ways of developing a quantum field: the path integral formalism and canonical quantization.^{[6]} The latter of these is pursued in this article.
Lagrangian formalism
Quantum field theory frequently makes use of the Lagrangian formalism from classical field theory. This formalism is analogous to the Lagrangian formalism used in classical mechanics to solve for the motion of a particle under the influence of a field. In classical field theory, one writes down a Lagrangian density, <math>\mathcal{L}</math>, involving a field, φ(x,t), and possibly its first derivatives (∂φ/∂t and ∇φ), and then applies a fieldtheoretic form of the Euler–Lagrange equation. Writing coordinates (t, x) = (x^{0}, x^{1}, x^{2}, x^{3}) = x^{μ}, this form of the Euler–Lagrange equation is^{[3]}
 <math>\frac{\partial}{\partial x^\mu} \left[\frac{\partial\mathcal{L}}{\partial(\partial\phi/\partial x^\mu)}\right]  \frac{\partial\mathcal{L}}{\partial\phi} = 0,</math>
where a sum over μ is performed according to the rules of Einstein notation.
By solving this equation, one arrives at the "equations of motion" of the field.^{[3]} For example, if one begins with the Lagrangian density
 <math> \mathcal{L}(\phi,\nabla\phi) = \rho(t,\mathbf{x})\,\phi(t,\mathbf{x})  \frac{1}{8\pi G}\nabla\phi^2,</math>
and then applies the Euler–Lagrange equation, one obtains the equation of motion
 <math> 4\pi G \rho(t,\mathbf{x}) = \nabla^2 \phi.</math>
This equation is Newton's law of universal gravitation, expressed in differential form in terms of the gravitational potential φ(t, x) and the mass density ρ(t, x). Despite the nomenclature, the "field" under study is the gravitational potential, φ, rather than the gravitational field, g. Similarly, when classical field theory is used to study electromagnetism, the "field" of interest is the electromagnetic fourpotential (V/c, A), rather than the electric and magnetic fields E and B.
Quantum field theory uses this same Lagrangian procedure to determine the equations of motion for quantum fields. These equations of motion are then supplemented by commutation relations derived from the canonical quantization procedure described below, thereby incorporating quantum mechanical effects into the behavior of the field.
Single and manyparticle quantum mechanics
In quantum mechanics, a particle (such as an electron or proton) is described by a complex wavefunction, ψ(x, t), whose timeevolution is governed by the Schrödinger equation:
 <math>\frac{{\hbar}^2}{2m}\frac{{\partial}^2}{\partial x^2}\psi(x,t) + V(x)\psi(x,t) = i \hbar \frac{\partial}{\partial t} \psi(x,t).</math>
Here m is the particle's mass and V(x) is the applied potential. Physical information about the behavior of the particle is extracted from the wavefunction by constructing expected values for various quantities; for example, the expected value of the particle's position is given by integrating ψ^{*}(x) x ψ(x) over all space, and the expected value of the particle's momentum is found by integrating −iħψ^{*}(x)dψ/dx. The quantity ψ^{*}(x)ψ(x) is itself in the Copenhagen interpretation of quantum mechanics interpreted as a probability density function. This treatment of quantum mechanics, where a particle's wavefunction evolves against a classical background potential V(x), is sometimes called first quantization.
This description of quantum mechanics can be extended to describe the behavior of multiple particles, so long as the number and the type of particles remain fixed. The particles are described by a wavefunction ψ(x_{1}, x_{2}, …, x_{N}, t), which is governed by an extended version of the Schrödinger equation.
Often one is interested in the case where N particles are all of the same type (for example, the 18 electrons orbiting a neutral argon nucleus). As described in the article on identical particles, this implies that the state of the entire system must be either symmetric (bosons) or antisymmetric (fermions) when the coordinates of its constituent particles are exchanged. This is achieved by using a Slater determinant as the wavefunction of a fermionic system (and a Slater permanent for a bosonic system), which is equivalent to an element of the symmetric or antisymmetric subspace of a tensor product.
For example, the general quantum state of a system of N bosons is written as
 <math> \phi_1 \cdots \phi_N \rang = \sqrt{\frac{\prod_j N_j!}{N!}} \sum_{p\in S_N} \phi_{p(1)}\rang \otimes \cdots \otimes \phi_{p(N)} \rang,</math>
where <math>\phi_i\rang</math> are the singleparticle states, N_{j} is the number of particles occupying state j, and the sum is taken over all possible permutations p acting on N elements. In general, this is a sum of N! (N factorial) distinct terms. <math>\sqrt{\frac{\prod_j N_j!}{N!}}</math> is a normalizing factor.
There are several shortcomings to the above description of quantum mechanics, which are addressed by quantum field theory. First, it is unclear how to extend quantum mechanics to include the effects of special relativity.^{[7]} Attempted replacements for the Schrödinger equation, such as the Klein–Gordon equation or the Dirac equation, have many unsatisfactory qualities; for instance, they possess energy eigenvalues that extend to –∞, so that there seems to be no easy definition of a ground state. It turns out that such inconsistencies arise from relativistic wavefunctions not having a welldefined probabilistic interpretation in position space, as probability conservation is not a relativistically covariant concept. The second shortcoming, related to the first, is that in quantum mechanics there is no mechanism to describe particle creation and annihilation;^{[8]} this is crucial for describing phenomena such as pair production, which result from the conversion between mass and energy according to the relativistic relation E = mc^{2}.
Second quantization
In this section, we will describe a method for constructing a quantum field theory called second quantization. This basically involves choosing a way to index the quantum mechanical degrees of freedom in the space of multiple identicalparticle states. It is based on the Hamiltonian formulation of quantum mechanics.
Several other approaches exist, such as the Feynman path integral,^{[9]} which uses a Lagrangian formulation. For an overview of some of these approaches, see the article on quantization.
Bosons
For simplicity, we will first discuss second quantization for bosons, which form perfectly symmetric quantum states. Let us denote the mutually orthogonal singleparticle states which are possible in the system by <math>\phi_1\rang, \phi_2\rang, \phi_3\rang,</math> and so on. For example, the 3particle state with one particle in state <math>\phi_1\rang</math> and two in state <math>\phi_2\rang</math> is
 <math> \frac{1}{\sqrt{3}} \left[ \phi_1\rang \phi_2\rang
\phi_2\rang + \phi_2\rang \phi_1\rang \phi_2\rang + \phi_2\rang \phi_2\rang \phi_1\rang \right]. </math>
The first step in second quantization is to express such quantum states in terms of occupation numbers, by listing the number of particles occupying each of the singleparticle states <math>\phi_1\rang, \phi_2\rang, </math> etc. This is simply another way of labelling the states. For instance, the above 3particle state is denoted as
 <math> 1, 2, 0, 0, 0, \dots \rangle.</math>
An Nparticle state belongs to a space of states describing systems of N particles. The next step is to combine the individual Nparticle state spaces into an extended state space, known as Fock space, which can describe systems of any number of particles. This is composed of the state space of a system with no particles (the socalled vacuum state, written as <math>0\rang</math>), plus the state space of a 1particle system, plus the state space of a 2particle system, and so forth. States describing a definite number of particles are known as Fock states: a general element of Fock space will be a linear combination of Fock states. There is a onetoone correspondence between the occupation number representation and valid boson states in the Fock space.
At this point, the quantum mechanical system has become a quantum field in the sense we described above. The field's elementary degrees of freedom are the occupation numbers, and each occupation number is indexed by a number <math>j</math> indicating which of the singleparticle states <math>\phi_1\rang, \phi_2\rang,\dots,\phi_j\rang,\dots</math> it refers to:
 <math>  N_1, N_2, N_3, \dots, N_j, \dots \rang .</math>
The properties of this quantum field can be explored by defining creation and annihilation operators, which add and subtract particles. They are analogous to ladder operators in the quantum harmonic oscillator problem, which added and subtracted energy quanta. However, these operators literally create and annihilate particles of a given quantum state. The bosonic annihilation operator <math>a_2</math> and creation operator <math>a_2^\dagger</math> are easily defined in the occupation number representation as having the following effects:
 <math> a_2  N_1, N_2, N_3, \dots \rang = \sqrt{N_2} \mid N_1, (N_2  1), N_3, \dots \rang,</math>
 <math> a_2^\dagger  N_1, N_2, N_3, \dots \rang = \sqrt{N_2 + 1} \mid N_1, (N_2 + 1), N_3, \dots \rang.</math>
It can be shown that these are operators in the usual quantum mechanical sense, i.e. linear operators acting on the Fock space. Furthermore, they are indeed Hermitian conjugates, which justifies the way we have written them. They can be shown to obey the commutation relation
 <math>
\left[a_i , a_j \right] = 0 \quad,\quad \left[a_i^\dagger , a_j^\dagger \right] = 0 \quad,\quad \left[a_i , a_j^\dagger \right] = \delta_{ij}, </math>
where <math>\delta</math> stands for the Kronecker delta. These are precisely the relations obeyed by the ladder operators for an infinite set of independent quantum harmonic oscillators, one for each singleparticle state. Adding or removing bosons from each state is therefore analogous to exciting or deexciting a quantum of energy in a harmonic oscillator.
Applying an annihilation operator <math>a_k</math> followed by its corresponding creation operator <math>a_k^\dagger</math> returns the number <math>N_k</math> of particles in the k^{th} singleparticle eigenstate:
 <math>a_k^\dagger\,a_k\dots, N_k, \dots \rangle=N_k \dots, N_k, \dots \rangle.</math>
The combination of operators <math>a_k^\dagger a_k</math> is known as the number operator for the k^{th} eigenstate.
The Hamiltonian operator of the quantum field (which, through the Schrödinger equation, determines its dynamics) can be written in terms of creation and annihilation operators. For instance, for a field of free (noninteracting) bosons, the total energy of the field is found by summing the energies of the bosons in each energy eigenstate. If the k^{th} singleparticle energy eigenstate has energy <math>E_k</math> and there are <math>N_k</math> bosons in this state, then the total energy of these bosons is <math>E_k N_k</math>. The energy in the entire field is then a sum over <math>k</math>:
 <math> E_\mathrm{tot} = \sum_k E_k N_k</math>
This can be turned into the Hamiltonian operator of the field by replacing <math>N_k</math> with the corresponding number operator, <math>a_k^\dagger a_k</math>. This yields
 <math>H = \sum_k E_k \, a^\dagger_k \,a_k.</math>
Fermions
It turns out that a different definition of creation and annihilation must be used for describing fermions. According to the Pauli exclusion principle, fermions cannot share quantum states, so their occupation numbers N_{i} can only take on the value 0 or 1. The fermionic annihilation operators c and creation operators <math>c^\dagger</math> are defined by their actions on a Fock state thus
 <math> c_j  N_1, N_2, \dots, N_j = 0, \dots \rangle = 0 </math>
 <math> c_j  N_1, N_2, \dots, N_j = 1, \dots \rangle = (1)^{(N_1 + \cdots + N_{j1})}  N_1, N_2, \dots, N_j = 0, \dots \rangle </math>
 <math> c_j^\dagger  N_1, N_2, \dots, N_j = 0, \dots \rangle = (1)^{(N_1 + \cdots + N_{j1})}  N_1, N_2, \dots, N_j = 1, \dots \rangle </math>
 <math> c_j^\dagger  N_1, N_2, \dots, N_j = 1, \dots \rangle = 0. </math>
These obey an anticommutation relation:
 <math>
\left\{c_i , c_j \right\} = 0 \quad,\quad \left\{c_i^\dagger , c_j^\dagger \right\} = 0 \quad,\quad \left\{c_i , c_j^\dagger \right\} = \delta_{ij}. </math>
One may notice from this that applying a fermionic creation operator twice gives zero, so it is impossible for the particles to share singleparticle states, in accordance with the exclusion principle.
Field operators
We have previously mentioned that there can be more than one way of indexing the degrees of freedom in a quantum field. Second quantization indexes the field by enumerating the singleparticle quantum states. However, as we have discussed, it is more natural to think about a "field", such as the electromagnetic field, as a set of degrees of freedom indexed by position.
To this end, we can define field operators that create or destroy a particle at a particular point in space. In particle physics, these operators turn out to be more convenient to work with, because they make it easier to formulate theories that satisfy the demands of relativity.
Singleparticle states are usually enumerated in terms of their momenta (as in the particle in a box problem.) We can construct field operators by applying the Fourier transform to the creation and annihilation operators for these states. For example, the bosonic field annihilation operator <math>\phi(\mathbf{r})</math> is
 <math>\phi(\mathbf{r}) \ \stackrel{\mathrm{def}}{=}\ \sum_{j} e^{i\mathbf{k}_j\cdot \mathbf{r}} a_{j}. </math>
The bosonic field operators obey the commutation relation
 <math>
\left[\phi(\mathbf{r}) , \phi(\mathbf{r'}) \right] = 0 \quad,\quad \left[\phi^\dagger(\mathbf{r}) , \phi^\dagger(\mathbf{r'}) \right] = 0 \quad,\quad \left[\phi(\mathbf{r}) , \phi^\dagger(\mathbf{r'}) \right] = \delta^3(\mathbf{r}  \mathbf{r'}) </math>
where <math>\delta(x)</math> stands for the Dirac delta function. As before, the fermionic relations are the same, with the commutators replaced by anticommutators.
The field operator is not the same thing as a singleparticle wavefunction. The former is an operator acting on the Fock space, and the latter is a quantummechanical amplitude for finding a particle in some position. However, they are closely related, and are indeed commonly denoted with the same symbol. If we have a Hamiltonian with a space representation, say
 <math>H =  \frac{\hbar^2}{2m} \sum_i \nabla_i^2 + \sum_{i < j} U(\mathbf{r}_i  \mathbf{r}_j) </math>
where the indices i and j run over all particles, then the field theory Hamiltonian (in the nonrelativistic limit and for negligible selfinteractions) is
 <math>H =  \frac{\hbar^2}{2m} \int d^3\!r \ \phi^\dagger(\mathbf{r}) \nabla^2 \phi(\mathbf{r}) + \frac{1}{2}\int\!d^3\!r \int\!d^3\!r' \; \phi^\dagger(\mathbf{r}) \phi^\dagger(\mathbf{r}') U(\mathbf{r}  \mathbf{r}') \phi(\mathbf{r'}) \phi(\mathbf{r}). </math>
This looks remarkably like an expression for the expectation value of the energy, with <math>\phi</math> playing the role of the wavefunction. This relationship between the field operators and wavefunctions makes it very easy to formulate field theories starting from spaceprojected Hamiltonians.
Dynamics
Once the Hamiltonian operator is obtained as part of the canonical quantization process, the time dependence of the state is described with the Schrödinger equation, just as with other quantum theories. Alternatively, the Heisenberg picture can be used where the time dependence is in the operators rather than in the states.
Implications
Unification of fields and particles
20px  This section requires expansion. (July 2009) 
The "second quantization" procedure that we have outlined in the previous section takes a set of singleparticle quantum states as a starting point. Sometimes, it is impossible to define such singleparticle states, and one must proceed directly to quantum field theory. For example, a quantum theory of the electromagnetic field must be a quantum field theory, because it is impossible (for various reasons) to define a wavefunction for a single photon.^{[10]} In such situations, the quantum field theory can be constructed by examining the mechanical properties of the classical field and guessing the corresponding quantum theory. For free (noninteracting) quantum fields, the quantum field theories obtained in this way have the same properties as those obtained using second quantization, such as welldefined creation and annihilation operators obeying commutation or anticommutation relations.
Quantum field theory thus provides a unified framework for describing "fieldlike" objects (such as the electromagnetic field, whose excitations are photons) and "particlelike" objects (such as electrons, which are treated as excitations of an underlying electron field), so long as one can treat interactions as "perturbations" of free fields. There are still unsolved problems relating to the more general case of interacting fields that may or may not be adequately described by perturbation theory. For more on this topic, see Haag's theorem.
Physical meaning of particle indistinguishability
The second quantization procedure relies crucially on the particles being identical. We would not have been able to construct a quantum field theory from a distinguishable manyparticle system, because there would have been no way of separating and indexing the degrees of freedom.
Many physicists prefer to take the converse interpretation, which is that quantum field theory explains what identical particles are. In ordinary quantum mechanics, there is not much theoretical motivation for using symmetric (bosonic) or antisymmetric (fermionic) states, and the need for such states is simply regarded as an empirical fact. From the point of view of quantum field theory, particles are identical if and only if they are excitations of the same underlying quantum field. Thus, the question "why are all electrons identical?" arises from mistakenly regarding individual electrons as fundamental objects, when in fact it is only the electron field that is fundamental.
Particle conservation and nonconservation
During second quantization, we started with a Hamiltonian and state space describing a fixed number of particles (N), and ended with a Hamiltonian and state space for an arbitrary number of particles. Of course, in many common situations N is an important and perfectly welldefined quantity, e.g. if we are describing a gas of atoms sealed in a box. From the point of view of quantum field theory, such situations are described by quantum states that are eigenstates of the number operator <math>\hat{N}</math>, which measures the total number of particles present. As with any quantum mechanical observable, <math>\hat{N}</math> is conserved if it commutes with the Hamiltonian. In that case, the quantum state is trapped in the Nparticle subspace of the total Fock space, and the situation could equally well be described by ordinary Nparticle quantum mechanics. (Strictly speaking, this is only true in the noninteracting case or in the low energy density limit of renormalized quantum field theories)
For example, we can see that the freeboson Hamiltonian described above conserves particle number. Whenever the Hamiltonian operates on a state, each particle destroyed by an annihilation operator <math>a_k</math> is immediately put back by the creation operator <math>a_k^\dagger</math>.
On the other hand, it is possible, and indeed common, to encounter quantum states that are not eigenstates of <math>\hat{N}</math>, which do not have welldefined particle numbers. Such states are difficult or impossible to handle using ordinary quantum mechanics, but they can be easily described in quantum field theory as quantum superpositions of states having different values of N. For example, suppose we have a bosonic field whose particles can be created or destroyed by interactions with a fermionic field. The Hamiltonian of the combined system would be given by the Hamiltonians of the free boson and free fermion fields, plus a "potential energy" term such as
 <math>H_I = \sum_{k,q} V_q (a_q + a_{q}^\dagger) c_{k+q}^\dagger c_k,</math>
where <math>a_k^\dagger</math> and <math>a_k</math> denotes the bosonic creation and annihilation operators, <math>c_k^\dagger</math> and <math>c_k</math> denotes the fermionic creation and annihilation operators, and <math>V_q</math> is a parameter that describes the strength of the interaction. This "interaction term" describes processes in which a fermion in state k either absorbs or emits a boson, thereby being kicked into a different eigenstate <math>k+q</math>. (In fact, this type of Hamiltonian is used to describe interaction between conduction electrons and phonons in metals. The interaction between electrons and photons is treated in a similar way, but is a little more complicated because the role of spin must be taken into account.) One thing to notice here is that even if we start out with a fixed number of bosons, we will typically end up with a superposition of states with different numbers of bosons at later times. The number of fermions, however, is conserved in this case.
In condensed matter physics, states with illdefined particle numbers are particularly important for describing the various superfluids. Many of the defining characteristics of a superfluid arise from the notion that its quantum state is a superposition of states with different particle numbers. In addition, the concept of a coherent state (used to model the laser and the BCS ground state) refers to a state with an illdefined particle number but a welldefined phase.
Axiomatic approaches
The preceding description of quantum field theory follows the spirit in which most physicists approach the subject. However, it is not mathematically rigorous. Over the past several decades, there have been many attempts to put quantum field theory on a firm mathematical footing by formulating a set of axioms for it. These attempts fall into two broad classes.
The first class of axioms, first proposed during the 1950s, include the Wightman, Osterwalder–Schrader, and Haag–Kastler systems. They attempted to formalize the physicists' notion of an "operatorvalued field" within the context of functional analysis, and enjoyed limited success. It was possible to prove that any quantum field theory satisfying these axioms satisfied certain general theorems, such as the spinstatistics theorem and the CPT theorem. Unfortunately, it proved extraordinarily difficult to show that any realistic field theory, including the Standard Model, satisfied these axioms. Most of the theories that could be treated with these analytic axioms were physically trivial, being restricted to lowdimensions and lacking interesting dynamics. The construction of theories satisfying one of these sets of axioms falls in the field of constructive quantum field theory. Important work was done in this area in the 1970s by Segal, Glimm, Jaffe and others.
During the 1980s, a second set of axioms based on geometric ideas was proposed. This line of investigation, which restricts its attention to a particular class of quantum field theories known as topological quantum field theories, is associated most closely with Michael Atiyah and Graeme Segal, and was notably expanded upon by Edward Witten, Richard Borcherds, and Maxim Kontsevich. However, most of the physically relevant quantum field theories, such as the Standard Model, are not topological quantum field theories; the quantum field theory of the fractional quantum Hall effect is a notable exception. The main impact of axiomatic topological quantum field theory has been on mathematics, with important applications in representation theory, algebraic topology, and differential geometry.
Finding the proper axioms for quantum field theory is still an open and difficult problem in mathematics. One of the Millennium Prize Problems—proving the existence of a mass gap in Yang–Mills theory—is linked to this issue.
Associated phenomena
In the previous part of the article, we described the most general features of quantum field theories. Some of the quantum field theories studied in various fields of theoretical physics involve additional special ideas, such as renormalizability, gauge symmetry, and supersymmetry. These are described in the following sections.
Renormalization
Early in the history of quantum field theory, it was found that many seemingly innocuous calculations, such as the perturbative shift in the energy of an electron due to the presence of the electromagnetic field, give infinite results. The reason is that the perturbation theory for the shift in an energy involves a sum over all other energy levels, and there are infinitely many levels at short distances that each give a finite contribution which results in a divergent series.
Many of these problems are related to failures in classical electrodynamics that were identified but unsolved in the 19th century, and they basically stem from the fact that many of the supposedly "intrinsic" properties of an electron are tied to the electromagnetic field that it carries around with it. The energy carried by a single electron—its self energy—is not simply the bare value, but also includes the energy contained in its electromagnetic field, its attendant cloud of photons. The energy in a field of a spherical source diverges in both classical and quantum mechanics, but as discovered by Weisskopf with help from Furry, in quantum mechanics the divergence is much milder, going only as the logarithm of the radius of the sphere.
The solution to the problem, presciently suggested by Stueckelberg, independently by Bethe after the crucial experiment by Lamb, implemented at one loop by Schwinger, and systematically extended to all loops by Feynman and Dyson, with converging work by Tomonaga in isolated postwar Japan, comes from recognizing that all the infinities in the interactions of photons and electrons can be isolated into redefining a finite number of quantities in the equations by replacing them with the observed values: specifically the electron's mass and charge: this is called renormalization. The technique of renormalization recognizes that the problem is essentially purely mathematical, that extremely short distances are at fault. In order to define a theory on a continuum, first place a cutoff on the fields, by postulating that quanta cannot have energies above some extremely high value. This has the effect of replacing continuous space by a structure where very short wavelengths do not exist, as on a lattice. Lattices break rotational symmetry, and one of the crucial contributions made by Feynman, Pauli and Villars, and modernized by 't Hooft and Veltman, is a symmetrypreserving cutoff for perturbation theory (this process is called regularization). There is no known symmetrical cutoff outside of perturbation theory, so for rigorous or numerical work people often use an actual lattice.
On a lattice, every quantity is finite but depends on the spacing. When taking the limit of zero spacing, we make sure that the physically observable quantities like the observed electron mass stay fixed, which means that the constants in the Lagrangian defining the theory depend on the spacing. Hopefully, by allowing the constants to vary with the lattice spacing, all the results at long distances become insensitive to the lattice, defining a continuum limit.
The renormalization procedure only works for a certain class of quantum field theories, called renormalizable quantum field theories. A theory is perturbatively renormalizable when the constants in the Lagrangian only diverge at worst as logarithms of the lattice spacing for very short spacings. The continuum limit is then well defined in perturbation theory, and even if it is not fully well defined nonperturbatively, the problems only show up at distance scales that are exponentially small in the inverse coupling for weak couplings. The Standard Model of particle physics is perturbatively renormalizable, and so are its component theories (quantum electrodynamics/electroweak theory and quantum chromodynamics). Of the three components, quantum electrodynamics is believed to not have a continuum limit, while the asymptotically free SU(2) and SU(3) weak hypercharge and strong color interactions are nonperturbatively well defined.
The renormalization group describes how renormalizable theories emerge as the long distance lowenergy effective field theory for any given highenergy theory. Because of this, renormalizable theories are insensitive to the precise nature of the underlying highenergy shortdistance phenomena. This is a blessing because it allows physicists to formulate low energy theories without knowing the details of high energy phenomenon. It is also a curse, because once a renormalizable theory like the standard model is found to work, it gives very few clues to higher energy processes. The only way high energy processes can be seen in the standard model is when they allow otherwise forbidden events, or if they predict quantitative relations between the coupling constants.
Haag's theorem
From a mathematically rigorous perspective, there exists no interaction picture in a Lorentzcovariant quantum field theory. This implies that the perturbative approach of Feynman diagrams in QFT is not strictly justified, despite producing vastly precise predictions validated by experiment. This is called Haag's theorem, but most particle physicists relying on QFT largely shrug it off.
Gauge freedom
A gauge theory is a theory that admits a symmetry with a local parameter. For example, in every quantum theory the global phase of the wave function is arbitrary and does not represent something physical. Consequently, the theory is invariant under a global change of phases (adding a constant to the phase of all wave functions, everywhere); this is a global symmetry. In quantum electrodynamics, the theory is also invariant under a local change of phase, that is – one may shift the phase of all wave functions so that the shift may be different at every point in spacetime. This is a local symmetry. However, in order for a welldefined derivative operator to exist, one must introduce a new field, the gauge field, which also transforms in order for the local change of variables (the phase in our example) not to affect the derivative. In quantum electrodynamics this gauge field is the electromagnetic field. The change of local gauge of variables is termed gauge transformation. It is worth noting that by Noether's theorem, for every such symmetry there exists an associated conserved current. The aforementioned symmetry of the wavefunction under global phase changes implies the conservation of electric charge.
In quantum field theory the excitations of fields represent particles. The particle associated with excitations of the gauge field is the gauge boson, which is the photon in the case of quantum electrodynamics.
The degrees of freedom in quantum field theory are local fluctuations of the fields. The existence of a gauge symmetry reduces the number of degrees of freedom, simply because some fluctuations of the fields can be transformed to zero by gauge transformations, so they are equivalent to having no fluctuations at all, and they therefore have no physical meaning. Such fluctuations are usually called "nonphysical degrees of freedom" or gauge artifacts; usually some of them have a negative norm, making them inadequate for a consistent theory. Therefore, if a classical field theory has a gauge symmetry, then its quantized version (i.e. the corresponding quantum field theory) will have this symmetry as well. In other words, a gauge symmetry cannot have a quantum anomaly. If a gauge symmetry is anomalous (i.e. not kept in the quantum theory) then the theory is nonconsistent: for example, in quantum electrodynamics, had there been a gauge anomaly, this would require the appearance of photons with longitudinal polarization and polarization in the time direction, the latter having a negative norm, rendering the theory inconsistent; another possibility would be for these photons to appear only in intermediate processes but not in the final products of any interaction, making the theory nonunitary and again inconsistent (see optical theorem).
In general, the gauge transformations of a theory consist of several different transformations, which may not be commutative. These transformations are together described by a mathematical object known as a gauge group. Infinitesimal gauge transformations are the gauge group generators. Therefore the number of gauge bosons is the group dimension (i.e. number of generators forming a basis).
All the fundamental interactions in nature are described by gauge theories. These are:
 Quantum chromodynamics, whose gauge group is SU(3). The gauge bosons are eight gluons.
 The electroweak theory, whose gauge group is U(1) × SU(2), (a direct product of U(1) and SU(2)).
 Gravity, whose classical theory is general relativity, admits the equivalence principle, which is a form of gauge symmetry. However, it is explicitly nonrenormalizable.
Multivalued gauge transformations
The gauge transformations which leave the theory invariant involve, by definition, only singlevalued gauge functions <math>\Lambda(x_i)</math> which satisfy the Schwarz integrability criterion
 <math>\partial_{x_i x_j} \Lambda = \partial_{x_jx_i} \Lambda.</math>
An interesting extension of gauge transformations arises if the gauge functions <math>\Lambda(x_i)</math> are allowed to be multivalued functions which violate the integrability criterion. These are capable of changing the physical field strengths and are therefore no proper symmetry transformations. Nevertheless, the transformed field equations describe correctly the physical laws in the presence of the newly generated field strengths. See the textbook by H. Kleinert cited below for the applications to phenomena in physics.
Supersymmetry
Supersymmetry assumes that every fundamental fermion has a superpartner that is a boson and vice versa. It was introduced in order to solve the socalled Hierarchy Problem, that is, to explain why particles not protected by any symmetry (like the Higgs boson) do not receive radiative corrections to its mass driving it to the larger scales (GUT, Planck...). It was soon realized that supersymmetry has other interesting properties: its gauged version is an extension of general relativity (Supergravity), and it is a key ingredient for the consistency of string theory.
The way supersymmetry protects the hierarchies is the following: since for every particle there is a superpartner with the same mass, any loop in a radiative correction is cancelled by the loop corresponding to its superpartner, rendering the theory UV finite.
Since no superpartners have yet been observed, if supersymmetry exists it must be broken (through a socalled soft term, which breaks supersymmetry without ruining its helpful features). The simplest models of this breaking require that the energy of the superpartners not be too high; in these cases, supersymmetry is expected to be observed by experiments at the Large Hadron Collider. The Higgs particle has been detected at the LHC, and no such superparticles have been discovered.
See also
 Abraham–Lorentz force
 Basic concepts of quantum mechanics
 Common integrals in quantum field theory
 Constructive quantum field theory
 Einstein–Maxwell–Dirac equations
 Feynman path integral
 Form factor (quantum field theory)
 Fundamental equation of unified field theory
 Green–Kubo relations
 Green's function (manybody theory)
 Invariance mechanics
 List of quantum field theories
 Pauli exclusion principle
 Photon polarization
 Pseudoscalar Field
 Quantum field theory in curved spacetime
 Quantum flavordynamics
 Quantum geometrodynamics
 Quantum hydrodynamics
 Quantum magnetodynamics
 Quantum triviality
 Relation between Schrödinger's equation and the path integral formulation of quantum mechanics
 Relationship between string theory and quantum field theory
 Schwinger–Dyson equation
 Static forces and virtualparticle exchange
 Symmetry in quantum mechanics
 Theoretical and experimental justification for the Schrödinger equation
 Ward–Takahashi identity
 Wheeler–Feynman absorber theory
 Wigner's classification
 Wigner's theorem
Notes
References
 ^ "Beautiful Minds, Vol. 20: Ed Witten". la Repubblica. 2010. Retrieved 22 June 2012. See here.
 ^ J. J. Thorn et al. (2004). Observing the quantum behavior of light in an undergraduate laboratory. . J. J. Thorn, M. S. Neel, V. W. Donato, G. S. Bergreen, R. E. Davies, and M. Beck. American Association of Physics Teachers, 2004.DOI: 10.1119/1.1737397.
 ^ ^{a} ^{b} ^{c} ^{d} David Tong, Lectures on Quantum Field Theory, chapter 1.
 ^ Srednicki, Mark. Quantum Field Theory (1st ed.). p. 19.
 ^ Srednicki, Mark. Quantum Field Theory (1st ed.). pp. 25–6.
 ^ Zee, Anthony. Quantum Field Theory in a Nutshell (2nd ed.). p. 61.
 ^ David Tong, Lectures on Quantum Field Theory, Introduction.
 ^ Zee, Anthony. Quantum Field Theory in a Nutshell (2nd ed.). p. 3.
 ^ Abraham Pais, Inward Bound: Of Matter and Forces in the Physical World ISBN 0198519974. Pais recounts how his astonishment at the rapidity with which Feynman could calculate using his method. Feynman's method is now part of the standard methods for physicists.
 ^ Newton, T.D.; Wigner, E.P. (1949). "Localized states for elementary systems". Reviews of Modern Physics 21 (3): 400–406. Bibcode:1949RvMP...21..400N. doi:10.1103/RevModPhys.21.400.
Further reading
 General readers
 Feynman, R.P. (2001) [1964]. The Character of Physical Law. MIT Press. ISBN 0262560038.
 Feynman, R.P. (2006) [1985]. QED: The Strange Theory of Light and Matter. Princeton University Press. ISBN 0691125759.
 Gribbin, J. (1998). Q is for Quantum: Particle Physics from A to Z. Weidenfeld & Nicolson. ISBN 0297817523.
 Schumm, Bruce A. (2004) Deep Down Things. Johns Hopkins Univ. Press. Chpt. 4.
 Introductory texts
 McMahon, D. (2008). Quantum Field Theory. McGrawHill. ISBN 9780071543828.
 Bogoliubov, N.; Shirkov, D. (1982). Quantum Fields. BenjaminCummings. ISBN 0805309837.
 Frampton, P.H. (2000). Gauge Field Theories<span />. Frontiers in Physics (2nd ed.). Wiley.
 Greiner, W; Müller, B. (2000). Gauge Theory of Weak Interactions. Springer. ISBN 3540676724.
 Itzykson, C.; Zuber, J.B. (1980). Quantum Field Theory. McGrawHill. ISBN 0070320713.
 Kane, G.L. (1987). Modern Elementary Particle Physics. Perseus Books. ISBN 0201117495.
 Kleinert, H.; SchulteFrohlinde, Verena (2001). Critical Properties of φ^{4}Theories. World Scientific. ISBN 9810246587.
 Kleinert, H. (2008). Multivalued Fields in Condensed Matter, Electrodynamics, and Gravitation (PDF). World Scientific. ISBN 9789812791702.
 Loudon, R (1983). The Quantum Theory of Light. Oxford University Press. ISBN 0198511558.
 Mandl, F.; Shaw, G. (1993). Quantum Field Theory. John Wiley & Sons. ISBN 9780471941866.
 Peskin, M.; Schroeder, D. (1995). An Introduction to Quantum Field Theory. Westview Press. ISBN 0201503972.
 Ryder, L.H. (1985). Quantum Field Theory. Cambridge University Press. ISBN 052133859X.
 Schwartz, M.D. (2014). Quantum Field Theory and the Standard Model. Cambridge University Press. ISBN 9781107034730.
 Srednicki, Mark (2007) Quantum Field Theory. Cambridge Univ. Press.
 Ynduráin, F.J. (1996). Relativistic Quantum Mechanics and Introduction to Field Theory (1st ed.). Springer. ISBN 9783540604532.
 Zee, A. (2003). Quantum Field Theory in a Nutshell. Princeton University Press. ISBN 0691010196.
 Advanced texts
 Brown, Lowell S. (1994). Quantum Field Theory. Cambridge University Press. ISBN 9780521469463.
 Bogoliubov, N.; Logunov, A.A.; Oksak, A.I.; Todorov, I.T. (1990). General Principles of Quantum Field Theory. Kluwer Academic Publishers. ISBN 9780792305408.
 Weinberg, S. (1995). The Quantum Theory of Fields 1–3. Cambridge University Press.
Articles:
 Gerard 't Hooft (2007) "The Conceptual Basis of Quantum Field Theory" in Butterfield, J., and John Earman, eds., Philosophy of Physics, Part A. Elsevier: 661–730.
 Frank Wilczek (1999) "Quantum field theory", Reviews of Modern Physics 71: S83–S95. Also doi=10.1103/Rev. Mod. Phys. 71.
External links
 Hazewinkel, Michiel, ed. (2001), "Quantum field theory", Encyclopedia of Mathematics, Springer, ISBN 9781556080104
 Stanford Encyclopedia of Philosophy: "Quantum Field Theory", by Meinard Kuhlmann.
 Siegel, Warren, 2005. Fields. A free text, also available from arXiv:hepth/9912205.
 Quantum Field Theory by P. J. Mulders
