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Threose

Threose[1]
150px
D-Threose
150px
L-Threose
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IUPAC names
(2S,3R)-2,3,4-Trihydroxybutanal (D)
(2R,3S)-2,3,4-Trihydroxybutanal (L)
Other names
Threotetrose
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95-43-2 (D) 7pxN
95-44-3 (L) 7pxY
ChEBI CHEBI:28587 7pxY
ChemSpider 388736 7pxY
Jmol-3D images Image

(D)
Image (L)

PubChem Template:Chembox PubChem/format
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C4H8O4
Molar mass Lua error in Module:Math at line 495: attempt to index field 'ParserFunctions' (a nil value). g·mol−1
Appearance Syrup
Very soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
 14pxN verify (what is10pxY/10pxN?)
Infobox references

Threose is a four-carbon monosaccharide or carbohydrate with molecular formula C4H8O4. It has a terminal aldehyde group rather than a ketone in its linear chain, and so is considered part of the aldose family of monosaccharides. The threose name can be used to refer to both the D- and L-stereoisomers, and more generally to the racemic mixture (D/L-, equal parts D- and L-) as well as to the more generic threose structure (absolute stereochemistry unspecified).

The prefix "threo" which derives from threose (and "erythro" from a corresponding diastereomer erythrose) offer a useful way to describe general organic structures with adjacent chiral centers, where "the prefixes... designate the relative configuration of the centers".[2] As is depicted in a Fischer projection of D-threose, the adjacent substituents will have a syn orientation in the isomer referred to as "threo", and are anti in the isomer referred to as "erythro".[2][3]

File:DL-Threose.svg
Fischer projections depicting the two enantiomers of threose

See also

References

  1. ^ Merck Index, 11th Edition, 9317
  2. ^ a b Formulas Using Other Configurational Notations, W. Rausch, accessed 1 March 2011
  3. ^ Prof. Rausch helpfully notes that the prefixes "may be applied to racemic compounds, as well as pure enantiomers and meso compounds", and that when depicted in the common "zig-zag" representation, adjacent "substituents may lie on the same side of the carbon chain... [syn] or on opposite sides... [anti]", which is opposite of their depiction in a Fischer projection.