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Tin(II) sulfide

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Tin(II) sulfide[1]
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IUPAC name
Tin(II) sulfide
Other names
Tin monosulfide
Herzenbergite
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1314-95-0 7pxN[[Category:Articles with changed CASNo identifier#REDIRECTmw:Help:Magic words#Other
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EC number 215-248-7
Jmol-3D images Image
PubChem Template:Chembox PubChem/format
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SnS
Molar mass 150.775 g/mol
Appearance dark brown solid
Density 5.22 g/cm3
Melting point Script error: No such module "convert".
Boiling point about 1230 ˚C
Insoluble
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Crystal structure GeS type (orthorhombic), oP8
Space group Pnma, No. 62
Lattice constant a = 11.18 Å, b = 3.98 Å, c = 4.32 Å[2]
asymmetric 3-fold (strongly distorted octahedral)
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Main hazards Irritant
EU Index Not listed
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Other anions
Tin(II) oxide
Tin selenide
Tin telluride
Other cations
Carbon monosulfide
Silicon monosulfide
Germanium monosulfide
Lead(II) sulfide
Related compounds
Tin(IV) sulfide
Tributyl tin sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Tin(II) sulfide is a chemical compound of tin and sulfur. The chemical formula is SnS. Its natural occurrence concerns herzenbergite, a rare mineral.

Synthesis

Tin(II) sulfide can be prepared by reacting tin with sulfur, or tin(II) chloride with hydrogen sulfide.

Sn + S → SnS
SnCl2 + H2S → SnS + 2HCl

Properties

Tin(II) sulfide is a brown solid, insoluble in water, but soluble in concentrated hydrochloric acid. Tin (II) sulfide is soluble in (NH4)2S. It has a layer structure similar to that of black phosphorus[3]

References

  1. ^ Record of Tin(II) sulfide in the GESTIS Substance Database of the IFA, accessed on 4/9/2007
  2. ^ del Bucchia, S.; Jumas, J.C.; Maurin, M. (1981). "Contribution a l'etude de composes sulfures d'etain (II): Affinement de la structure de Sn S". Acta Cryst. B 37: 1903. doi:10.1107/s0567740881007528. 
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 1233. ISBN 0080379419.