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Tin(IV) iodide

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Tin(IV) iodide

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IUPAC name
tin(IV) iodide
Other names
tin tetraiodide
stannic iodide
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7790-47-8 7pxN ChemSpider 23033 7pxN EC number 232-208-4 Jmol-3D images Image PubChem Template:Chembox PubChem/format colspan=2 style="background:#f8eaba; border-top:2px solid transparent; border-bottom:2px solid transparent; text-align:center;" #REDIRECTmw:Help:Magic words#Other
This page is a soft redirect. Properties

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SnI4 Molar mass 626.328 g mol−1 Appearance red-orange solid Density 4.56 g cm−3 Melting point Script error: No such module "convert". Boiling point Script error: No such module "convert". 2.106 colspan=2 style="background:#f8eaba; border-top:2px solid transparent; border-bottom:2px solid transparent; text-align:center;" #REDIRECTmw:Help:Magic words#Other
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Crystal structure Cubic, cP40 Space group P-43m, No. 205
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tin(IV) iodide, also known as stannic iodide, is the chemical compound with the formula SnI4. This tetrahedral molecule crystallises as a bright orange solid that dissolves readily in nonpolar solvents such as benzene.[1]

The compound is usually prepared by the reaction of iodine and tin:[2]

Sn + 2 I2 → SnI4

The compound hydrolyses in water.[3] In aqueous hydroiodic acid, it reacts to form a rare example of a metal hexaiodide:[2]

SnI4 + 2 I → [SnI6]2−

See also

References

  1. Chemistry : Periodic Table : tin : compound data [tin (IV) iodide]
  2. 2.0 2.1 Moeller, T., Edwards, D. C., Brandt, R. L. and Kleinberg, J. (1953). "Tin(IV) Iodide (Stannic Iodide)". Inorganic Syntheses. Inorganic Syntheses 4: 119–121. ISBN 978-0-470-13235-7. doi:10.1002/9780470132357.ch40. 
  3. Hickling, G. G. (1990). "Gravimetric analysis: The synthesis of tin iodide". J. Chem. Educ. 67 (8): 702–703. doi:10.1021/ed067p702.