Open Access Articles- Top Results for Vinyl

International Journal of Innovative Research in Science, Engineering and Technology
International Journal of Innovative Research in Science, Engineering and Technology
International Journal of Innovative Research in Science, Engineering and Technology
A Study on Aging Behaviour of Well-Dispersed Alumina Suspensions by Varying the Particle Size using Poly vinyl Butyral as Binder
International Journal of Advanced Research in Electrical, Electronics and Instrumentation Energy
Studies on the Electrical Conductivity Measurement of Organic/Organic Composite Polyvinyl alcohol/Polyaniline (PVA/PANI)


This article is about the chemistry term. For the plastic "vinyl", see polyvinyl chloride. For other uses, see Vinyl (disambiguation).
File:Vinyl group.png
Chemical structure of the vinyl functional group.

In chemistry, vinyl or ethenyl[1] is the functional groupCH=CH2, namely the ethylene molecule (H2C=CH2) minus one hydrogen atom. The name is also used for any compound containing that group, namely R−CH=CH2 where R is any other group of atoms.

An industrially important example is vinyl chloride, precursor to PVC, a plastic commonly known as vinyl.

Vinyl is one of the alkenyl functional groups. On a carbon skeleton, sp2-hybridized carbons or positions are often called vinylic. Allyls, acrylates and styrenics contain vinyl groups. (A styrenic crosslinker with two vinyl groups is called divinyl benzene.)


The etymology of vinyl is the Latin vinum = "wine", because of its relationship with alcohol (in its original sense of ethyl alcohol). The term "vinyl" was coined by the German chemist Hermann Kolbe in 1851.[2]

Vinyl polymers

Main article: Vinyl polymer

Vinyl groups can polymerize with the aid of a radical initiator or a catalyst, forming vinyl polymers. In these polymers, the double bonds of the vinyl monomers turn into single bonds and the different monomers are joined by single bonds. Vinyl groups do not exist in vinyl polymer; the term refers to the precursor. It is sometimes important to ascertain the absence of unreacted vinyl monomer in the final product when the monomer is toxic or reduces the performance of the plastic. The following table gives some examples of vinyl polymers.

Monomer example Example of resulting polymer
Vinyl chloride Polyvinyl chloride (PVC)
Vinyl fluoride Polyvinyl fluoride (PVF)
Vinyl acetate Polyvinyl acetate (PVAc)

The vinylidene and vinylene derivatives can polymerize in the same manner.


Vinyl derivatives are alkenes. If activated by an adjacent group, the increased polarization of the bond gives rise to characteristic reactivity, which is termed vinylogous:

  • In allyl compounds, where the next carbon is saturated but substituted once, allylic rearrangement and related reactions are observed.
    • Allyl Grignard reagents can attack with the vinyl end first.
  • If next to an electron-withdrawing group, conjugate addition (Michael addition) occurs.

Vinyl organometallics, e.g. vinyl lithium, participate in coupling reactions such as in Negishi coupling.

See also


  1. ^ IUPAC Provisional Recommendations 2004 Chapter 5
  2. ^ H. Kolbe (1851), "On the chemical constitution and nature of organic radicals," The Quarterly Journal of the Chemical Society of London, 3 (4) : 369-405; see footnote on page 376.